- Title
- Hierarchical Polyimide-Covalent Organic Frameworks Carbon Fiber Structures Enhancing Physical and Electrochemical Properties
- Creator
- Coia, Piers; Dharmasiri, Bhagya; Henderson, Luke C.; Hayne, David J.; Borkar, Ameya; Hua, Carol; Austria, Elmer; Akhavan, Behnam; Judicpa, Mia Angela Nuñeza; Usman, Ken Aldren Sumaya; Razal, Joselito
- Relation
- Small Structures Vol. 5, Issue 10, no. 2400166
- Publisher Link
- http://dx.doi.org/10.1002/sstr.202400166
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA
- Resource Type
- journal article
- Date
- 2024
- Description
- The multifunctionality of carbon fiber (CF) is being extensively explored. Herein, polyimide covalent organic frameworks (PI-COFs) are grafted bound to CF to enhance their mechanical and electrochemical properties. Here, a range of COF scaffolds are grafted to the surface of CFs via a two-step functionalization. First, melamine is tethered to the fiber surface to provide an anchoring point for the COFs followed by a “graft from” approach to grow three different sized PI-COFs utilizing three differently sized dianhydride, PMDA to form MA-PMDA, NTCDA to form MA-NTCDA, and PTCDA to form MA-PTCDA COFs. These COFs increase the capacitance of CF by a maximum of 2.9 F g−1 (480% increase) for the MA-PTCDA, this coincides with an increase in interfacial shear strength by 67.5% and 52% for MA-NTCDA and MA-PTCDA, respectively. This data represents that the first-time CF has been modified with PI-COFs and allows access to COF properties including their porosity and CO2 capture ability while being attached to a substrate. This may lead to additional high-value recyclability and second-life applications for CFs.
- Subject
- carbon fibers; covalent organic frameworks; energy storages; surface modifications; SDG 13; Sustainable Development Goal
- Identifier
- http://hdl.handle.net/1959.13/1511792
- Identifier
- uon:56542
- Identifier
- ISSN:2688-4062
- Rights
- © 2024 The Author(s). Small Structures published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Language
- eng
- Full Text
- Reviewed
- Hits: 246
- Visitors: 252
- Downloads: 7
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | ATTACHMENT01 | Publisher version (open access) | 8 MB | Adobe Acrobat PDF | View Details Download |